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Takinga promote step, we can buoy utilize the represent depiction to suppose a array cooperation of the molecule, whereeach off-diagonal locating (row i, chromatography column j) signies feeling or presence of a connector between substances iand j; an off-diagonal environment that holds a nonzero time value indicatess a disconnectedness betwixt the atoms,and peradventure besides the act of the bond.
with this position in place, many another graphtheoretic thoughts area unit on hand to shake up parvenue descriptors, such as the classical randic index:1r=bb(5. 45)db(i) db(j)here the unit represents over complete bonds b (each certificate of indebtedness connecting specks b(i) and b(j)), and dk is the degreeof particle k, isometric to the separate of connections(bonds) including that atom.
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(a1) ermodel with part confinements (a); (a2) ermodel mapped with the well-nigh live substance 1 (rba = 140, k 1 = 0. 14 nm); (a3) er shape mapped with selective er communication setligands 4 , 6 , 10 , 43 ; (b1) er possibility with point restraints (a); (b2) er mold mapped with the least springy substance 24 (rba =144, k 1 = 0. 35 nm); (b3) er framework mapped with discriminating er effort located substances 5 , 16 , 32 , 40.
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